Out of desperation I start to do all sorts of stuff with users and shares on the DNS just to see if I can make something changed. I even deleted all shares. After rebooting it reinstated Volume_1 and Volume_2, it obviously does not like no shares. At some point in time in all this I noticed in the putty window that all the file permissions were NO LONGER rwxrwxrwx, but I can't remember exactly what it was. Seeing this change I then proceded with the "chmod -R 777", and guess what it works now!!!
If I had the time I would try to retrace my steps in an effort to try to repeat the issue and nail down the fix, if not work out the cause. Unfortunately I only have two drives and now that it is all working I don't won't to risk my production data.
If in the future I manage to borrow a couple of sata drives I'll see if I can repeat it. Otherwise, I am just happy that it all works as it should now.
Z